Redox reactions
Oxidation can be described as the reaction with oxygen. Respiration is an example of an oxidation reaction. The reaction is shown below.
C6H12O6 + 6 O2 → 6 CO2 + 6 H2O
From your earlier studies, you should know some other definitions of oxidation and reduction. Write down any definitions that you know, discussing your ideas with others or your teacher if you have the opportunity. Click the link below to reveal more.
Did you get the following?
Oxidation:
- the gain of oxygen
- the loss of electrons
- the increase in oxidation number.
Reduction:
- the loss of oxygen
- the gain of hydrogen
- the gain of electrons
- the decrease in oxidation number.
Did you also say that reduction and oxidation reactions always occur together and can, therefore, be described as redox reactions?
You have seen that oxidation and reduction are the reverse of each other, and one cannot occur without the other. In a redox reaction there is always a substance being oxidised and a substance being reduced. The best way to investigate redox reactions at this stage is by considering the transfer of electrons.
Text Reference: Read Section 9.1 and answer Review Exercise 9.1
In the following reactions, identify the substances being oxidised.
Text alternative to the burning magnesium video
Magnesium ribbon burns in air with bright white flame.
Click here to open the video in a new window.
1 |
Reaction 1: Burning magnesium2 Mg + O2 → 2 MgO |
Text alternative to the forming silver video
Silver forms on a copper wire which is placed in a blue solution of copper(II) sulfate.
Click here to open the video in a new window.
2 |
Reaction 2: Forming silverCu + 2 AgCl → CuCl2 + 2 Ag |
Text alternative to the copper hydroxide video
A blue precipitate is formed in a solution.
Click here to open the video in a new window.
3 |
Reaction 3: Forming copper(II) hydroxideCuSO4 + 2 NaOH → Cu(OH)2 + Na2SO4 |
Half-equations
You should recall that we can use half-equations to show the oxidation and reduction processes occurring in redox reactions. Write half-equations in your notes for the reactions in the above activity that were redox reactions.
Once you have done this, click the link below.
You should have the following.
Reaction 1: Burning magnesium
Oxidation: Mg → Mg2+ + 2 e-
Reduction: O2 + 4 e- → 2 O2-
Reaction 2: Forming silver
Oxidation: Cu → Cu2+ + 2 e-
Reduction: Ag+ + e- → Ag
(Reaction 3 was a precipitation reaction, not a redox reaction)
Sometimes it is helpful to use the concept of oxidation number to determine whether a redox reaction is occurring, and to identify what is being oxidised and reduced in the process. The next section will revise the idea of oxidation number and use oxidation numbers to reveal the changes occurring in more redox reactions.