Oxidation numbers
Before we see how we can use oxidation numbers, let's see whether you have remembered how to assign oxidation numbers. Complete the following revision activity to test your skills of assigning oxidation numbers (or oxidation states).
Activity: Assigning oxidation numbers
Work out the oxidation number of the underlined element in the following substances.
1 |
Carbon dioxideCO2 |
2 |
Sulfate ionSO42- |
3 |
Magnesium metalMg |
4 |
Copper(II) sulfideCuS |
Congratulations if you got all of these correct.
You can access the rules for assigning oxidation numbers here .
If you think you need more practice with these, complete the questions here .
Using oxidation numbers
Oxidation numbers are values that are assigned to atoms to help with working out what is happening to substances during redox reactions. Once you have worked out the oxidation number of an element, the following rules can be applied.
An increase in oxidation number means that the element is being oxidised.
A decrease in oxidation number means that the element is being reduced.
To practise using this idea, complete the following questions based on two redox reactions.
Equation:
CH4 + 2 O2 → CO2 + 2 H2O
5 |
How does the oxidation number of carbon change during this reaction? |
6 |
How does the oxidation number of oxygen change during this reaction? |
7 |
Which element is being reduced in this reaction? |
Text alternative to the acid and magnesium video
Magnesium metal dissolving in hydrochloric acid.
Click here to open the video in a new window.
Equation:
2 HCl + Mg → MgCl2 + H2
or 2 H+ + Mg → Mg2+(aq) + H2(g)
8 |
How does the oxidation number of magnesium change during this reaction? |
9 |
How does the oxidation number of chlorine change during this reaction? |
10 |
Which element is being reduced in this reaction? |
- If respiration is an oxidation reaction, is photosynthesis a reduction reaction?
- In respiration, what are the changes occurring to the oxidation numbers of the elements involved in the process?