Structure of alcohols

Alcohols can be classified as three different types (primary, secondary and tertiary) based on their structure. The most important carbon atom in organic molecules is often the carbon atom which is attached to the functional group. This is because when the compound reacts, it is often the bonding of this carbon atom which changes.

In the case of alcohols this atom can be described as the alcoholic carbon atom. This is shown in the following diagram.

alcoholic carbon atom highlighted in a butan-2-ol molecule

The classification of the alcohols is based on how many other carbon atoms are attached to the alcoholic carbon atom. Watch the videos which show examples of the three types of alcohols.

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Text alternative to the primary alcohol video

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Text alternative to the secondary alcohol video

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Text alternative to the tertiary alcohol video

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Complete the Summary worksheet Opens a 62kBMicrosoft® Word document in a new browser window. which asks you to draw two-dimensional structures of the alcohols in the videos, and draw and name one other example of each type.

Being able to distinguish between the types of alcohols is important as the different types will behave in different ways as you will see in the following sections.